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Chemistry · Electrochemical Cell

Voltaic Cell Diagram

A voltaic cell converts the free energy of a spontaneous redox reaction into electrical energy. This is a chemistry cell, not a biological cell.

Voltaic Cell DiagramA voltaic cell converts the free energy of a spontaneous redox reaction into electrical energy. This is a chemistry cell, not a biological cell.01Anode (−)02Cathode (+)03Salt bridge04External wire05Electrolytes

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Diagram labels and functions

Structure / stageFunction
Anode (−)Oxidation releases electrons.
Cathode (+)Reduction accepts electrons.
Salt bridgeMaintains charge balance between half-cells.
External wireCarries electrons from anode to cathode.
ElectrolytesSolutions containing reacting ions.

How a voltaic cell works

Oxidation at the negative anode releases electrons into the wire. They travel to the positive cathode, where reduction consumes them.

Why a salt bridge is needed

Without ion movement, charge would quickly build up and stop electron flow. The salt bridge completes the internal circuit while keeping the half-cell solutions mostly separate.

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Frequently Asked Questions

What is a voltaic cell?

An electrochemical cell that generates electricity from a spontaneous redox reaction.

Which way do electrons flow?

From the anode through the external circuit to the cathode.

Is a voltaic cell the same as a galvanic cell?

Yes. The two names describe the same type of spontaneous electrochemical cell.

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